Published July 15, 2002
| Supplemental Material
Journal Article
Open
Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen
Abstract
The oxidation of (tmeda)Pt^(II)(CH_3)_2 (1, tmeda = N,N,N',N'-tetramethylethylenediamine) to (tmeda)Pt^(IV)(OH)(OCH_3)(CH_3)_2 (3) by dioxygen in methanol proceeds via a two-step mechanism. The initial reaction between (tmeda)Pt(CH_3)_2 and dioxygen yields a hydroperoxoplatinum(IV) intermediate, (tmeda)Pt(OOH)(OCH_3)(CH_3)_2 (2), which reacts with a second equivalent of (tmeda)Pt(CH_3)_2 to afford the final product 3. Both 2 and 3 have been fully characterized, including X-ray crystallographic structure determinations. The effect of ligand variation on the oxidation of several dimethylplatinum(II) complexes by 2 as well as by dioxygen has been examined.
Additional Information
© 2002 American Chemical Society. Received December 18, 2001. Publication Date (Web): June 12, 2002. Support by the National Science Foundation (Grant No. CHE-9807496), Akzo-Nobel, and BP are gratefully acknowledged. We wish to thank Drs. William Schaefer and Richard Marsh for help with X-ray structure determinations and Professor John Eiler for help with mass spectrometry measurements. We also gratefully acknowledge Flavio Grynszpan for the cover art design.Attached Files
Supplemental Material - ic0112903.cif
Supplemental Material - ic0112903_s.pdf
Files
ic0112903_s.pdf
Files
(862.3 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:50b1da3f85d7ca0a4d9ef5825a825d0f
|
31.7 kB | Download |
|
md5:677f1c8ab522e30cc3f944c556d753e1
|
830.6 kB | Preview Download |
Additional details
- Eprint ID
- 75268
- DOI
- 10.1021/ic0112903
- Resolver ID
- CaltechAUTHORS:20170321-100112771
- CHE-9807496
- NSF
- Akzo-Nobel
- BP
- Created
-
2017-03-21Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field