Published April 20, 2005
| Supplemental Material
Journal Article
Open
The Direct Acyl-Alkylation of Arynes
- Creators
- Tambar, Uttam K.
-
Stoltz, Brian M.
Abstract
An efficient and mild acyl-alkylation of arynes is described. The method is used to synthesize medium-sized carbocycles by the ring-expansion of cyclic β-ketoesters.
Additional Information
© 2005 American Chemical Society. Received 9 February 2005. Published online 26 March 2005. Published in print 1 April 2005. This work is dedicated to our friend and colleague Professor John D. Roberts, the father of benzyne.8 We are grateful to the NDSEG (predoctoral fellowship to U.K.T.), the A. P. Sloan Foundation, the Research Corporation, Pfizer, Novartis, Merck, Amgen, Lilly, Roche, Abbott, AstraZeneka, GlaxoSmithKline, and Caltech for financial support.Attached Files
Supplemental Material - ja050859msi20050306_053600.pdf
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Additional details
- Eprint ID
- 74457
- Resolver ID
- CaltechAUTHORS:20170222-085357234
- National Defense Science and Engineering Graduate (NDSEG) Fellowship
- Alfred P. Sloan Foundation
- Research Corporation
- Pfizer
- Novartis
- Merck
- Amgen
- Lilly
- Roche
- Abbott
- AstraZeneca
- GlaxoSmithKline
- Caltech
- Created
-
2017-02-22Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field