On the structure of the mixed ligand complex of [VO]^(2+) with hydrotris(3,5-dimethylpyrazolyl)borato and 1,3-diphenyl-1,3-propanedionato ligands

Abstract

The structure of (1,3-diphenyl-1,3-propanedionato,κ^2O,O')oxo[tris(3,5-dimethyl-1-pyrazolyl-κN^2)hydroborato] vanadium(IV) methyl cyanide, [VO(C_(15)H_(22)-BN_6)(C_(15)H_(11)O_2)].xCH_3CN, has recently been described and refined [Beddoes, Eardley, Mabbs, Moorcroft & Passand (1993). Acta Cryst. C49, 1923-1926] in space group Pna2_1 (orthorhombic; a = 15.960 (1), b = 12.447 (1), c = 17.044 (1) Å, z = 4). It is better described in Pnma (conventional setting of Pnam). Revised coordinates are given and the anomalous bond lengths reported earlier are revised.

Files

Additional details