Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published January 1, 1972 | Published
Journal Article Open

Mixed Magnetic and Electric Dipole Transition in s-Triazine

Abstract

We have shown that the radiation pattern for absorption to the lowest energy excited singlet state of s‐triazine corresponds to that of a mixed electric and magnetic dipole transition. This was done by demonstrating, for the first time with an organic, the classic procedure of obtaining absorption coefficients for different k, ε̂, and Ĥ for a uniaxial arrangement of molecules. We find the 30 014 cm^(−1) transition of s‐triazine to be 26% magnetic and 74% electric dipole, hence the state symmetry is ^1 E in the crystal field, and ^1 E″ in the free molecule (D_(3h) ).

Additional Information

© 1972 The American Institute of Physics. Received 12 August 1971. This research was supported by a Department of Health Grant GM 12592 and by the Laboratory for Research on the Structure of Matter through an A.R.P.A. grant to the University of Pennsylvania.

Attached Files

Published - 1.1676916.pdf

Files

1.1676916.pdf
Files (527.2 kB)
Name Size Download all
md5:98d5e1578fc4f549f5bf8dd2e576a86c
527.2 kB Preview Download

Additional details

Created:
August 19, 2023
Modified:
October 20, 2023