Published January 1, 1972
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Journal Article
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Mixed Magnetic and Electric Dipole Transition in s-Triazine
Chicago
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Abstract
We have shown that the radiation pattern for absorption to the lowest energy excited singlet state of s‐triazine corresponds to that of a mixed electric and magnetic dipole transition. This was done by demonstrating, for the first time with an organic, the classic procedure of obtaining absorption coefficients for different k, ε̂, and Ĥ for a uniaxial arrangement of molecules. We find the 30 014 cm^(−1) transition of s‐triazine to be 26% magnetic and 74% electric dipole, hence the state symmetry is ^1 E in the crystal field, and ^1 E″ in the free molecule (D_(3h) ).
Additional Information
© 1972 The American Institute of Physics. Received 12 August 1971. This research was supported by a Department of Health Grant GM 12592 and by the Laboratory for Research on the Structure of Matter through an A.R.P.A. grant to the University of Pennsylvania.Attached Files
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Additional details
- Eprint ID
- 70632
- Resolver ID
- CaltechAUTHORS:20160928-081727482
- NIH
- GM 12592
- Advanced Research Projects Agency (ARPA)
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2016-09-28Created from EPrint's datestamp field
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2021-11-11Created from EPrint's last_modified field