Published December 16, 1983
| public
Journal Article
Diphenylbutadiene in supersonic jets: Spectroscopy and picosecond dynamics
- Creators
- Shepanski, J. F.
- Keelan, B. W.
- Zewail, A. H.
Chicago
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Abstract
The picosecond dynamics and one- and two-photon excitation of jet-cooled diphenylbutadiene are reported. An A_g^* state is found to lie below the dipole allowed B_u^* state. Isomerization and/or other non-radiative processes are important above a threshold of 1050 cm^(−1) excess energy. Results are compared with those previously obtained for stilbene.
Additional Information
© 1983 Elsevier B.V. Received 8 September 1983, in final form 26 October 1983. The authors gratefully acknowledge the support of this work by the National Science Foundation under Grant No. CHE-8211356. We thank Peter M. Felker and Lutfur R. Khundkar for their assistance in the lifetime measurements, and Robert R. Birge and Wm. A. Goddard III for helpful and stimulating discussions.Additional details
- Eprint ID
- 70485
- Resolver ID
- CaltechAUTHORS:20160921-075401066
- NSF
- CHE-8211356
- Created
-
2016-09-28Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 6703