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Published July 15, 1993 | Published + Supplemental Material
Journal Article Open

Copper(II) tetrakis(pentafluorophenyl)-β-octachloroporphyrin

Abstract

The title compound, {4,5,9,10,14,15,19,20-octachloro-2,7,12, 17-tetrakis(pentafluorophenyl)-20,22,23,24- tetraazapentacyclo[l6.2.l.1^(3·6).l^(8·11).l^(13·16)]tetracosa-1,3(21),4,6,8(22),9,11, 13(23), 14, 16, 18(24), 19-dodecaene}copper(II)(CuTFPPC1_8)dichloromethane solvate, shows a large tetrahedral distortion or ruffling, with pairs of Cl atoms alternately averaging + 1.20 and -1.18 Å out of the plane of the four N atoms; the Cu atom is 0.01 Å out of the plane and the N atoms show a slight (±0.12 Å) tetrahedral distortion. A Cl atom of the solvent, at 3.515 (6) Å in an approximately axial position, is the closest non-bonded neighbor of the Cu atom.

Additional Information

© 1993 International Union of Crystallography. Received 6 May 1992; accepted 15 January 1993. This work was supported by the US Department of Energy, Morgantown Energy Technology Center, the Gas Research Institute, and the Sun Company, Inc.

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Supplemental Material - hh1022.cif

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Created:
August 20, 2023
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