Published September 28, 1977
| public
Journal Article
Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides
- Creators
- Jones, Carol R.
-
Dervan, Peter B.
Abstract
We report the syntheses and thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides (1 and 2, respectively). These initial findings provide the first stereochemical study of six-membered cyclic diacyl peroxide thermal fragmentations. The data presented here are consistent with a common intermediate(s) but do not require the generation of electronically excited states of the 2-butene products.
Additional Information
© 1977 American Chemical Society. Publication Date: September 1977. Received May 19, 1977. We are grateful to the National Science Foundation (CHE75-06776) and the National Institutes of Health for generous financial support.Additional details
- Eprint ID
- 67112
- DOI
- 10.1021/ja00462a058
- Resolver ID
- CaltechAUTHORS:20160516-094425023
- CHE75-06776
- NSF
- NIH
- Created
-
2016-05-16Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Crellin Laboratory of Chemistry
- Other Numbering System Identifier
- 5588