Published January 15, 1980
| public
Journal Article
Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes
- Creators
- Schultz, Peter G.
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Dervan, Peter B.
Chicago
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Abstract
We report the synthesis, infrared and electronic spectra, and the kinetics of the thermal decomposition of N-(2,2,5,5-tetramethylpyrrolidyl)nitrene (1). Because the six-membered ring 1,1-diazene 2 has been characterized, these results allow some estimate of the importance of structure on the spectral properties and kinetic behavior of 1,1-dialkyldiazenes. In addition, the first approximate heat of formation of a 1,1-diazene from experiment is provided.
Additional Information
© 1980 American Chemical Society. Received August 13, 1979. Publication Date: January 1980. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research.Additional details
- Eprint ID
- 67102
- DOI
- 10.1021/ja00522a090
- Resolver ID
- CaltechAUTHORS:20160516-092521832
- NSF
- CHE75-06776
- American Chemical Society Petroleum Research Fund
- Created
-
2016-05-16Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Crellin Laboratory of Chemistry
- Other Numbering System Identifier
- 6065