Published March 15, 2009
| Published
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1-(Trifluoromethyl)vinyllithium
- Creators
- Chang, Shuh-Kuen
- Other:
- Fuchs, Philip L.
Abstract
InChI = 1S/C3H2F3.Li/c1-2-3(4,5)6;/h1H2; InChIKey = YDBNXCHLLXTABG-UHFFFAOYSA-N (reagent used as a versatile vinylation component) Physical Data: thermally unstable; decomposes quickly at temperatures above −78 °C. Solubility: soluble in diethyl ether, pentane, and THF. Form Supplied in: not available commercially. Preparative Method: prepared from the reaction of commercially available 2-bromo-3,3,3-trifluoropropene with n-, sec-, or tert-butyllithium in diethyl ether at −100 to −110 °C. Handling, Storage, and Precautions: prepared and transferred at low temperature (≤ −100 °C) under inert atmosphere (Ar); air and moisture sensitive; handle in fume hood.
Additional Information
© 2001 John Wiley & Sons, Ltd. Published Online: 15 MAR 2009. Encyclopedia entry includes InChi structural models.Attached Files
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- Resolver ID
- CaltechAUTHORS:20160404-083705705
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