Spatial patterns and source attribution of urban methane in the Los Angeles Basin
Abstract
Urban areas are increasingly recognized as a globally important source of methane to the atmosphere; however, the location of methane sources and relative contributions of source sectors are not well known. Recent atmospheric measurements in Los Angeles, California, USA, show that more than a third of the city's methane emissions are unaccounted for in inventories and suggest that fugitive fossil emissions are the unknown source. We made on-road measurements to quantify fine-scale structure of methane and a suite of complementary trace gases across the Los Angeles Basin in June 2013. Enhanced methane levels were observed across the basin but were unevenly distributed in space. We identified 213 methane hot spots from unknown emission sources. We made direct measurements of ethane to methane (C_2H_6/CH_4) ratios of known methane emission sources in the region, including cattle, geologic seeps, landfills, and compressed natural gas fueling stations, and used these ratios to determine the contribution of biogenic and fossil methane sources to unknown hot spots and to local urban background air. We found that 75% of hot spots were of fossil origin, 20% were biogenic, and 5% of indeterminate source. In regionally integrated air, we observed a wider range of C_2H_6/CH_4 values than observed previously. Fossil fuel sources accounted for 58–65% of methane emissions, with the range depending on the assumed C_2H_6/CH_4 ratio of source end-members and model structure. These surveys demonstrated the prevalence of fugitive methane emissions across the Los Angeles urban landscape and suggested that uninventoried methane sources were widely distributed and primarily of fossil origin.
Additional Information
© 2016 American Geophysical Union. Received 3 NOV 2015. Accepted 17 FEB 2016. Accepted article online 20 FEB 2016. Original geolocated, time-stamped trace gas measurements made by mobile laboratory are provided as Data Set S1. This research is funded by the U.S. Department of Energy's Office of Science (BER) under grant DE-SC0005266. This work was supported in part by the W. M. Keck Institute for Space Studies. We thank Valerie Carranza, Joshua Miu, Mariela Ruacho, Kristal Verhulst, Josette Marrero, and Tianyang Zhu for help with field work and Simone Meinardi for help in the laboratory.Attached Files
Published - jgrd52791.pdf
Supplemental Material - jgrd52791-sup-0001-SuppInfo.docx
Supplemental Material - jgrd52791-sup-0002-SuppInfo.zip
Supplemental Material - jgrd52791-sup-0003-SuppInfo-s03.txt
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Additional details
- Eprint ID
- 65441
- Resolver ID
- CaltechAUTHORS:20160317-132327182
- Department of Energy (DOE)
- DE-SC0005266
- Keck Institute for Space Studies (KISS)
- Created
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2016-03-17Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Caltech groups
- Keck Institute for Space Studies