Published July 23, 2007
| public
Journal Article
Distance-Independent DNA Charge Transport across an Adenine Tract
Abstract
Charging along: DNA-mediated charge transport across adenine tracts is monitored by using a probe interior to the bridge (N^6-cyclopropyladenine (^(CP)A), shown in red). This trap was incorporated serially across the bridge and could be oxidized by a distal rhodium photooxidant without significant attenuation in yield over a distance of 5 nm. These results are consistent with complete delocalization of charge across the DNA bridge.
Additional Information
© 2007 WILEY-VCH Verlag. Received: April 7, 2007 Revised: May 11, 2007. Article first published online: 2 Jul 2007. We are grateful to the NIH (GM49216) for their financial support. We thank M. Davis and F. Shao for expert assistance.Additional details
- Eprint ID
- 64385
- DOI
- 10.1002/anie.200701522
- Resolver ID
- CaltechAUTHORS:20160210-145408316
- GM49216
- NIH
- Created
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2016-02-10Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field