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Published April 8, 1966 | public
Journal Article

Oxygen Isotope Fractionation in the System Dolomite-Calcite-Carbon Dioxide

Abstract

Oxygen isotopes were equilibrated between carbon dioxide and calcite at four temperatures in the range 350° to 610°C and between carbon dioxide and dolomite at 350° and 400°C. Carbon of unusual isotopic composition was used as a tracer to demonstrate the nature and extent of the exchange process. Extrapolation of these data at lower temperatures indicates that at 25°C dolomite is enriched in oxygen-18 by 6.8 per mil with respect to calcite. This result indicates that those natural dolomite-calcite assemblages which show very small fractionations were not formed in isotopic equilibrium.

Additional Information

© 1966 American Association for the Advancement of Science. Received 7 February 1966. Supported by NSF grant No. GP 2254 and AEC contract No. AT (04-3)-427. Contribution No. 1396 of California Institute of Technology, Pasadena.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023