Published September 15, 1979
| public
Journal Article
On π-shell photoionization in molecular nitrogen
Abstract
Static-exchange calculations of π-shell photoionization in molecular nitrogen yield a physically incorrect description of the 1π_u → kπ_g partial-channel cross section; difficulties are attributed to spurious perturbations arising from the intense π → π^* intravalence transition. A simple projection procedure is devised that retains the computational simplicity of the frozen-core approximation and gives cross sections in good accord with measured values.
Additional Information
© 1979 Elsevier B.V. Received 18 June 1979. Work performed under the auspices of the U-S-Department of Energy at Lawrence Livermore Laboratory under contract No-W-7405-Eng-48.Additional details
- Eprint ID
- 62170
- DOI
- 10.1016/0009-2614(79)80380-2
- Resolver ID
- CaltechAUTHORS:20151117-122645391
- W-7405-Eng-48
- Department of Energy (DOE)
- Created
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2015-11-17Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field