Published February 1, 1967
| Published
Journal Article
Open
Calculation of Nuclear Magnetic Shielding Constants in Two Simple Systems
- Creators
- McKoy, Vincent
- Musher, Jeremy I.
Chicago
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Abstract
The nuclear magnetic shielding constants of two simple systems are calculated explicitly. These systems are (1) a nucleus μ at a distance R from a hydrogenic atom of charge ζe in the presence of an external electric field, and (2) a nucleus μ of a hydrogenic atom of charge ζe in the presence of a point charge at R with the result expanded in inverse powers of R. These calculations should prove useful in understanding the long‐range contributions of functional groups and neighboring molecules to observed chemical shifts of molecules.
Additional Information
© 1967 American Institute of Physics. (Received 2 September 1966) This research was supported in part by a grant from the National Science Foundation GP 5687. One of us (V.M.) would like to acknowledge the hospitality of the Rockefeller University, where some of this work was performed.Attached Files
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Additional details
- Eprint ID
- 61680
- Resolver ID
- CaltechAUTHORS:20151028-114741297
- NSF
- GP 5687
- Created
-
2015-10-28Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 3420