Published June 20, 2003
| Published
Journal Article
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Pump-Probe Photoionization Study of the Passage and Bifurcation of a Quantum Wave Packet Across an Avoided Crossing
Abstract
The application of femtosecond pump-probe photoelectron spectroscopy to directly observe vibrational wave packets passing through an avoided crossing is investigated using quantum wave packet dynamics calculations. Transfer of the vibrational wave packet between diabatic electronic surfaces, bifurcation of the wave packet, and wave packet construction via nonadiabatic mixing are shown to be observable as time-dependent splittings of peaks in the photoelectron spectra.
Additional Information
© 2003 American Physical Society. (Received 26 November 2002; published 19 June 2003) This work has been supported in part by a Grant-in-Aid for the 21st Century COE Program for Frontiers in Fundamental Chemistry from the Ministry of Education, Culture, Sports, Science and Technology (Japan), by the Mitsubishi Foundation, and by the National Science Foundation (U.S.A.).Attached Files
Published - PhysRevLett.90.248303.pdf
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PhysRevLett.90.248303.pdf
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Additional details
- Eprint ID
- 61597
- Resolver ID
- CaltechAUTHORS:20151027-154126138
- 21st Century COE Program for Frontiers in Fundamental Chemistry
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Mitsubishi Foundation
- NSF
- Created
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2015-10-28Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field