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Published October 15, 2003 | Published
Journal Article Open

Studies of electron transfer in NaI with pump–probe femtosecond photoelectron spectroscopy

Abstract

We discuss an extension of our formulation of energy- and angle-resolved photoelectron spectra for femtosecond pump–probe ionization of wave packets to nonadiabatically coupled states and present results of its applications to wave packet motion on the ionic (Na^+I^−) and covalent (NaI) states of sodium iodide. The results of these studies suggest that the energy and angular distributions of these photoelectron spectra provide a useful mapping of the bifurcation of the wave packets through the crossing region and a valuable window on the intramolecular electron transfer occurring between the covalent and ionic states (NaI→Na^+I^−).

Additional Information

© 2003 American Institute of Physics. (Received 5 June 2003; accepted 24 July 2003) This work was supported by grants from the 21st Century COE Program for Frontiers in Fundamental Chemistry of the Ministry of Education, Culture, Sports, Science, and Technology (Japan), the Mitsubishi Foundation, and the National Science Foundation (U.S.).

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August 19, 2023
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