Published August 1963
| public
Journal Article
Small-ring compounds—XXXVIII: Calculations of the relative stabilities of intermediates in the interconversion reactions of cyclopropylcarbinyl, cyclobutyl, and allylcarbinyl derivatives by the LCAO method
- Creators
- Howden, M. E. H.
- Roberts, John D.
Abstract
The simple LCAO method with corrections for angle strain indicates that bicyclobutonium cations are likely to be more stable than homoallylic cations. The reverse is predicted to be true for the corresponding free-radical and anionic derivatives. The results are in accord with experiment.
Additional Information
© 1963 Pergamon Press Ltd. Received 3 January 1962. Supported in part by the National Science Foundation; Contribution No. 2788 from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena, California.Additional details
- Eprint ID
- 61526
- DOI
- 10.1016/S0040-4020(63)80029-0
- Resolver ID
- CaltechAUTHORS:20151026-142340213
- NSF
- Created
-
2015-10-26Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2788