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Published 1967 | public
Journal Article

Internal-return rearrangement in solvolysis of cyclopropylcarbinyl derivatives

Abstract

The unusual reactivities of cyclopropylcarbinyl derivatives in solvolytic reactions have led to a continuing interest in the details of the reaction mechanism and the structures of the intermediates (1). Conductimetric (2) and titrimetric (3) methods for the rate determinations have increased the precision of the measured rate constants but reliance on kinetic data alone has led to some interpretative oversights.

Additional Information

© 1967 Pergamon Press Ltd. Received 30 January 1967. This work was supported in part by the National Science Foundation.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023