Published 1967
| public
Journal Article
Internal-return rearrangement in solvolysis of cyclopropylcarbinyl derivatives
- Creators
- Servis, Kenneth L.
- Roberts, John D.
Chicago
Abstract
The unusual reactivities of cyclopropylcarbinyl derivatives in solvolytic reactions have led to a continuing interest in the details of the reaction mechanism and the structures of the intermediates (1). Conductimetric (2) and titrimetric (3) methods for the rate determinations have increased the precision of the measured rate constants but reliance on kinetic data alone has led to some interpretative oversights.
Additional Information
© 1967 Pergamon Press Ltd. Received 30 January 1967. This work was supported in part by the National Science Foundation.Additional details
- Eprint ID
- 61522
- Resolver ID
- CaltechAUTHORS:20151026-114005600
- NSF
- Created
-
2015-10-26Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3470