Published October 1, 1951
| public
Journal Article
The Nature of the Intermediate in the Solvolysis of Norbornyl Derivatives
- Creators
- Roberts, John D.
- Lee, C. C.
Abstract
It has been suggested on the basis of solvolysis rate and stereochemical considerations that the solvolysis of exo- and endo-norbornyl p-bromobenzenesulfonates in acetic acid proceeds by a bridged "non-classical" carbonium ion having a structure (I) like that proposed for the cationic intermediate involved in the rearrangement of camphene hydrochloride to isobornyl chloride.
Additional Information
© 1951 American Chemical Society. Received August 20, 1951. Supported by the program of research of the U. S. Atomic Energy Commission under Contract AT(30-1)-905. Presented at the Symposium on Reaction Mechanisms at the 75th Anniversary Meeting of the American Chemical Society, September 7, 1951.Additional details
- Eprint ID
- 61443
- DOI
- 10.1021/ja01154a555
- Resolver ID
- CaltechAUTHORS:20151022-140105133
- AT(30-1)-905
- Atomic Energy Commission
- Created
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2015-10-22Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field