Published February 1, 1956
| public
Journal Article
The Mechanism of Aminations of Halobenzenes
Abstract
An elimination-addition mechanism, probably involving a "benzyne" intermediate, has been established for the rearrangements which often occur in the conversion of non-activated aryl halides to arylamines with metallic amides. The evidence for the "benzyne" intermediate was obtained through ^(14)C-tracer studies of rearrangements with halobenzenes and experiments designed to determine the role of the hydrogen atom located ortho to the displaced halogen atom.
Additional Information
© 1956 American Chemical Society. Received August 22, 1955. Supported in part by the program of research of the U. S. Atomic Energy Commission. Presented in part at the Kansas City Meeting of the American Chemical Society, March 24, 1954. Skinner Fellow of Mt. Holyoke College, 1953-1954; National Science Foundation Predoctoral Fellow, 1954-1955.Additional details
- Eprint ID
- 61381
- Resolver ID
- CaltechAUTHORS:20151021-125952657
- Atomic Energy Commission
- Mt. Holyoke College
- NSF Predoctoral Fellowship
- Created
-
2015-10-22Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2028