Published February 1, 1957
| public
Journal Article
Anomalous Spin-Spin Splitting in Nuclear Magnetic Resonance Spectra of Cyclobutenes
- Creators
- Sharts, Clay M.
- Roberts, John D.
Abstract
A spectacular failure of F-F spin-spin coupling constants, A_(ij), to decrease monotonically with the number of chemical bonds separating nuclei i and j has been deduced from the nuclear magnetic resonance (n.m.r.) spectrum of perfluorodimethylethylamine. The current importance attached to the use of n.m.r. spectra as a tool for establishment of organic structures prompts us to report a number of similarly anomalous H-F spin-spin coupling constants in cyclobutene derivatives.
Additional Information
© 1957 American Chemical Society. Received January 24, 1957. We are indebted to Drs. Y. Kitahara, R. E. Krall, E. F. Silversmith, E. J. Smutny, and Mr. S. Manatt for samples of many. This work was supported in part by the Office of Naval Research.Additional details
- Eprint ID
- 61367
- DOI
- 10.1021/ja01561a072
- Resolver ID
- CaltechAUTHORS:20151021-100828582
- Office of Naval Research (ONR)
- Created
-
2015-10-21Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2074