Nuclear Magnetic Resonance Spectra. Allylmagnesium Bromide
- Creators
- Nordlander, J. Eric
- Roberts, John D.
Abstract
The proton nuclear magnetic resonance (n.m.r.) spectrum of allylmagnesium bromide (I, Fig. 1) Fig. 1.-Proton magnetic resonance spectra of allylmagnesium bromide in diethyl ether solution (upper) and allylbenzene (lower). The spectra were taken with a Varian Associates High Resolution Spectrometer (V-4300) at 60 Mc. with a 12-inch magnet equipped with a Super-stabilizer. Chemical shifts are in C.P.S. from benzene (external reference) and were measured by the audio-oscillator sideband superposition method. The signals designated C_6H_(10) in the allylmagnesium bromide spectrum are due to diallyl formed by coupling during preparation of the Grignard reagent, as verified by the spectrum of a sample to which diallyl had been added deliberately.
Additional Information
© 1959 American Chemical Society. Received February 26, 1959. Supported in part by the Office of Naval Research.Additional details
- Eprint ID
- 61340
- Resolver ID
- CaltechAUTHORS:20151020-141342444
- Office of Naval Research (ONR)
- Created
-
2015-10-20Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2442