Published January 1, 1961 | public
Journal Article

Nuclear Magnetic Resonance Spectroscopy. The Structure of Butenylmagnesium Bromide

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Abstract

Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same butenyl Grignard reagent, which conceivably could be crotylmagnesium bromide (I), α-methylallyl-magnesium bromide (II), a more or less mobile equilibrium mixture of I and II, or an intermediate, bridged structure such as III.

Additional Information

© 1961 American Chemical Society. Received December 12, 1960. Supported in part by the Office of Naval Research.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023