Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published August 1, 1962 | public
Journal Article

Nuclear Magnetic Resonance Spectroscopy. Long-Range H-F Spin-Spin Coupling in 1,1-Difluoro-2,2-dichloro-3-phenyl-3-methylcyclobutane

Abstract

A 2 C.P.S. long-range H-F spin-spin coupling has been observed over fire saturated bonds in 1,1-difluoro-2,2-dichloro-3-phenyl-3-metliylcyclobutane, involving one of the fluorines at the 1-position and the protons of the 3-methyl group. Comparison of the spectrum with that of stereospecifically labeled 4-deuterio derivatives suggests that the fluorine involved in the long-range coupling is the one cis to the methyl group.

Additional Information

© 1962 American Chemical Society. Received March 7, 1962. Supported in part by the Kureha Chemical Ind. Co. (Japan) and the Office of Naval Research.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023