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Published May 1, 1962 | public
Journal Article

Nuclear Magnetic Resonance Spectroscopy. Long-Range Spin Couplings in Vinylacetylene

Abstract

The failure of long-range spin coupling to be observed in the high-resolution proton magnetic resonance spectra of vinylacetylene and propargylaldehyde has been cited as evidence against hyperconjugation as a mechanism for long-range coupling in unsaturated compounds. The reasoning involved has been challenged recently by Hoffman and Gronowitz on theoretical grounds.

Additional Information

© 1962 American Chemical Society. Received January 6, 1962. Supported in part by the Office of Naval Research and the Undergraduate Research Participation Program of the National Science Foundation.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023