Published October 1, 1963
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Cyclopropane Derivatives
Chicago
An error occurred while generating the citation.
Abstract
Chemical shifts and coupling constants have been determined from the analysis of proton nuclear magnetic resonance spectra for a series of cyclopropane derivatives. The geminal and vicinal cyclopropyl couplings have opposite signs. Additional ^(13)C-H coupling constants have been obtained for cyclopropanes which support the conclusion that the hybridization of the carbon-hydrogen bonding orbitals in cyclopropanes is close to sp. The chemical shifts for several cyclopropane hydrocarbons seem consistent with a ring-current effect.
Additional Information
© 1963 American Chemical Society. Received April 30, 1963. Supported in part by the Office of Naval Research and the National Science Foundation. Besides the generous gifts of samples of cyclopropane derivatives meritioned above, we are deeply grateful to Drs. A. A. Bothner-By, J. D. Swalen, and Professor K. B. Wiberg for supplying us with program decks for the calculation and fitting of n.m.r. spectra for use with the IBM 7090 computer. Mr. K. Servis and Mr. L. Sloan provided extensive help with the computations.Additional details
- Eprint ID
- 61205
- DOI
- 10.1021/ja00903a036
- Resolver ID
- CaltechAUTHORS:20151016-112437420
- Office of Naval Research (ONR)
- NSF
- Created
-
2015-10-16Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2964