Published March 1, 1965
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. The Effect of Solvent on Magnetic Nonequivalence Arising from Molecular Asymmetry
Chicago
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Abstract
The chemical shift between the geminal methylene protons of 1-phenylethyl benzyl ether has been measured in a variety of solvents. An approximate correlation observed between solvent dielectric constant and the degree of the magnetic nonequivalence of the methylene protons, V_A - V_B, is discussed in light of similar results for structurally related compounds. It is suggested that the variation in V_A - V_B with solvent may reflect changes in the conformation of the benzylic phenyl ring with respect to the methylene group.
Additional Information
© 1965 American Chemical Society. Received September 18, 1964. Supported in part by the Office of Naval Research and the undergraduate research participation program of the National Science Foundation; N.A.T.O. Fellow, 1963.Additional details
- Eprint ID
- 61198
- Resolver ID
- CaltechAUTHORS:20151016-101609996
- Office of Naval Research (ONR)
- NSF Undergraduate Research Program
- NATO fellowship
- Created
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2015-10-16Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3157