Published March 1, 1965
| public
Journal Article
Small-Ring Compounds. XLIII. Formolysis of Substituted Allylcarbinyl Tosylates
- Creators
- Servis, Kenneth L.
- Roberts, John D.
Chicago
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Abstract
Rate accelerations have been measured as a function of methyl substitution in 3- and 4-positions and phenyl substitution at the 4-position in the formolysis of allylcarbinyl tosylate. The largest factor, 4.5 x 10^3, was observed for (γ,γ dimethylallyl)carbinyl tosylate. The nature of the solvolytic transition state is discussed; the results are shown to be inconsistent with formation of classical carbonium ion intermediates.
Additional Information
© 1965 American Chemical Society. Received November 13, 1964. Supported in part by the National Science Foundation.Additional details
- Eprint ID
- 61196
- Resolver ID
- CaltechAUTHORS:20151016-100322036
- NSF
- Created
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2015-10-16Created from EPrint's datestamp field
- Updated
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2023-10-24Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3170