Published July 1, 1965
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Temperature Dependence of the Spectrum of Fluorocyclooctatetraene
Chicago
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Abstract
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent between 30 and 65º. This is attributed to changes in the rate of an inversion-bond-shift process which is slow on the n.m.r. time scale at low temperatures. The free energy of activation for inversion is approximately 12 kcal/mole at -33º.
Additional Information
© 1965 American Chemical Society. Received March 5, 1965. Supported in part by the Office of Naval Research.Additional details
- Eprint ID
- 61174
- Resolver ID
- CaltechAUTHORS:20151015-104930928
- Office of Naval Research (ONR)
- Created
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2015-10-15Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3184