Published July 1, 1965
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Temperature Dependence of the Spectrum of Fluorocyclooctatetraene
Abstract
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent between 30 and 65º. This is attributed to changes in the rate of an inversion-bond-shift process which is slow on the n.m.r. time scale at low temperatures. The free energy of activation for inversion is approximately 12 kcal/mole at -33º.
Additional Information
© 1965 American Chemical Society. Received March 5, 1965. Supported in part by the Office of Naval Research.Additional details
- Eprint ID
- 61174
- Resolver ID
- CaltechAUTHORS:20151015-104930928
- Office of Naval Research (ONR)
- Created
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2015-10-15Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3184