Published September 1, 1965
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Magnetic Nonequivalence Due to Slow Inversion in Amines
- Creators
- Griffith, Dean L.
- Roberts, John D.
Abstract
Investigation of the low-temperature n.m.r. spectrum of N-benzyl-O,N-dimethylhydroxylamine has permitted a determination of the rate and activation energy for nitrogen inversion. The energy barrier to inversion has been found to be inversely proportional to the solvent dielectric constant in four rather nonpolar solvents. In n-hexane, E_ɑ was found to be 12.9 ± 0.3 kcal. while in methylene chloride a value of 9.4 ± 0.4 kcal. was obtained.
Additional Information
© 1965 American Chemical Society. Received May 20, 1965. Supported in part by the National Science Foundation. National Science Foundation Postdoctoral Fellow, 1964-1965.Additional details
- Eprint ID
- 61168
- DOI
- 10.1021/ja01096a014
- Resolver ID
- CaltechAUTHORS:20151015-104929440
- NSF
- NSF Postdoctoral Fellowship
- Created
-
2015-10-16Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3250