Published July 1, 1965
| public
Journal Article
Magnetic Resonance Spectroscopy. The Configurational Stability of Primary Grignard Reagents. 3,3-Dimethylbutylmagnesium Chloride
Chicago
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Abstract
Detailed examination of the temperature dependence of the n.m.r. spectra of 3,3-dimethylbutylmagnesium chloride and bis(3,3-dimethylbutyl)magnesium indicates that inversion of configuration at the -CH_2Mg center occurs rapidly in ether solution at room temperature.
Additional Information
© 1965 American Chemical Society. Received January 9, 1965. Supported in part by the Office of Naval Research and the National Science Foundation. Presented at the 10th Reaction Mechanisms Conference, Corvallis, Ore., June 24, 1964.Additional details
- Eprint ID
- 61158
- DOI
- 10.1021/ja01091a014
- Resolver ID
- CaltechAUTHORS:20151015-104907132
- Office of Naval Research (ONR)
- NSF
- Created
-
2015-10-15Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3186