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Published February 1, 1967 | public
Journal Article

The Synthesis of Asymmetrically Labeled 5-Norbornene-2,3-endo-dicarboxylic Anhydride

Abstract

Procedures are described for a synthesis of 5-norbornene-2,3-endo-dicarboxylica nhydride stereospecifically labeled with ^(14)C in one carbonyl group and for the degradation of the anhydride to determine which carbonyl group was labeled. The particular method of synthesis was found to give the labeled anhydride with ^(14)C in that carbonyl group which corresponds in position to the carboxyl group of the levorotatory 2-endo-norbornanecarboxylic acid.

Additional Information

© 1967 American Chemical Society. Received May 23, 1966. Supported by the National Science Foundation.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023