Published June 1, 1967
| public
Journal Article
Evidence for Rapid and Reversible Equilibration of the γ,γ-Diphenylallylcarbinyl and Diphenylcyclopropylcarbinyl Free Radicals
Chicago
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Abstract
We wish to report an example of an unusually facile and reversible free-radical rearrangement in which a substituted allylcarbinyl free radical is interconverted with the corresponding cyclopropylcarbinyl radical. The investigation of the radical rearrangement complements previous studies on analogous carbanion and similar carbonium ion systems.
Additional Information
© 1967 American Chemical Society. Received January 30, 1967. Supported by the National Science Foundation. A preliminary account of the decomposition of t-butyl (γ,γ-diphenylallyl)peracetate and the theoretical problems posed thereby was presented at the Symposium on Small-Ring Compounds at the 142nd National Meeting of the American Chemical Society, Washington, D. C., March 22, 1962.Additional details
- Eprint ID
- 61113
- DOI
- 10.1021/ja00988a046
- Resolver ID
- CaltechAUTHORS:20151014-144940963
- NSF
- Created
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2015-10-15Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3415