Published October 1, 1969
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Effects of Molecular Asymmetry on Carbon-13 Chemical Shifts
Chicago
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Abstract
A nearby center of molecular asymmetry often induces magnetic nonequivalence of the protons of an isopropyl group (or of a methylene group), and this phenomenon has been the subject of many investigations. We report here the first observance of the effect of molecular asymmetry on the resonances of methyl carbons in isopropyl groups in compounds of the type (CH_3)_2-CH(CH_2)_nCHR_1R-2.
Additional Information
© 1969 American Chemical Society. Received June 18, 1969. Supported in part by the Public Health Service, Research Grant 11072-05-06 from the Division of General Medical Sciences, and the National Science Foundation. We are pleased to acknowledge the help and suggestions of Dr. Frank J. Weigert in the course of this work.Additional details
- Eprint ID
- 61068
- DOI
- 10.1021/ja01049a066
- Resolver ID
- CaltechAUTHORS:20151013-145410768
- U.S. Public Health Service (USPHS)
- 11072-05-06
- NSF
- Created
-
2015-10-14Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3872