Published March 1, 1970
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts in Cycloalkanones
- Creators
- Weigert, Frank J.
- Roberts, John D.
Chicago
Abstract
High-resolution ^(13)C nuclear magnetic resonance spectra have been obtained of a number of cycloalkanones. Simple additivity relationships were found which enable reasonable prediction of the chemical shifts of alkyl-substituted cyclohexanones. Attempts have been made to assign conformations to the higher cycloalkanones on the basis of their ^(13)C chemical shifts.
Additional Information
© 1970 American Chemical Society. Received June 26, 1969. Supported by the National Science Foundation and the Public Health Service, Research Grant No, 11072-05-06 from the Division of General Medical Sciences. National Science Foundation Predoctoral Fellow, 1965-1968. We are indebted to Professor David M. Grant for providing us with information about his research on ^(13)C chemical shifts in advance of publication. A sample of 2-t-butylcyclohexanone was generously lent to us by Professor Norman Allinger and the chemical shifts of this substance were measured by Dr. Manfred Jautelat.Additional details
- Eprint ID
- 61045
- DOI
- 10.1021/ja00708a039
- Resolver ID
- CaltechAUTHORS:20151013-111510505
- NSF
- U.S. Public Health Service (USPHS)
- 11072-05-06
- NSF Predoctoral Fellowship
- Created
-
2015-10-14Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3888