Published March 1972
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Ring Inversion in 1,1 -Difluorocyclodecane
- Creators
- Noe, Eric A.
- Roberts, John D.
Abstract
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-temperature ^(19)F nmr spectra. At -135º, the free energy of activation was 5.7 kcal/mol. The results are interpreted in terms of a boat-chair-boat conformation. Possible pathways for effecting ring inversion are discussed.
Additional Information
© 1972 American Chemical Society. Received July 1, 1971. Supported by the National Science Foundation. Summer National Science Foundation Fellow, 1966 and 1968; National Defense Education Act Trainee, 1968-1969.Additional details
- Eprint ID
- 60959
- Resolver ID
- CaltechAUTHORS:20151009-133527182
- NSF
- Summer National Science Foundation Fellow
- National Defense Education Act Trainee
- Created
-
2015-10-15Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4275