Published May 1, 1972
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Conformational Equilibriums and Equilibration of 3,3-Difluoro-Trans-cyclodecene
Abstract
On cooling 3,3-difluoro-trans-cyclodecene from room temperature to - 152º, three different processes which equilibrate cyclodecene conformations appear to become slow on the nmr time scale. At -152º, at least five out of eight possible conformational classes are present, four of which are separated by 0.8 kcal/mol or less. The free energy of activation for the slowest of the equilibration processes compares well with that for trans-cyclodecene itself.
Additional Information
© 1972 American Chemical Society. Received May 17, 1971. Supported by the National Science Foundation. National Science Foundation Summer Fellow, 1966 and 1968; National Defense Education Act Trainee, 1968-1969; (b) National Science Foundation Postdoctoral Fellow, 1970-1971.Additional details
- Eprint ID
- 60957
- DOI
- 10.1021/ja00765a040
- Resolver ID
- CaltechAUTHORS:20151009-133526647
- NSF
- NSF Summer Fellow
- National Defense Education Act Trainee
- NSF Postdoctoral Fellowship
- Created
-
2015-10-15Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4253