Published June 1, 1977
| public
Journal Article
Nitrogen-15 Magnetic Resonance Spectroscopy. Natural-Abundance Nitrogen-15 Spectra of Some 2-Amino-2-deoxy-D-hexose Derivatives
- Creators
- Botto, Robert E.
- Roberts, John D.
Chicago
Abstract
The nitrogen-15 nuclear magnetic resonance spectra of some 2-amino-2-deoxj D-hexose drochlorides and 2-acetamido-2-deoxy-D-hexoses and N-benzoyl-D-glucosamine are reported. The differences in chemical shifts for the various hexopyranose structures are discussed in terms of steric, stereoelectronic, and hydrogen-bonding effects. These model compounds were used to study substituent effects related to amino sugar containing polysaccharides and antibiotics.
Additional Information
© 1977 American Chemical Society. Received September 28, 1976. Supported by the Public Health Service, Research Grant GM-11072, from the Division of General Medical Sciences, and by the National Science Foundation.Additional details
- Eprint ID
- 60911
- DOI
- 10.1021/jo00433a012
- Resolver ID
- CaltechAUTHORS:20151008-115811190
- U.S. Public Health Service (USPHS)
- GM-11072
- NSF
- Created
-
2015-10-11Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 5438