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Published June 1, 1977 | public
Journal Article

Nitrogen-15 Magnetic Resonance Spectroscopy. Natural-Abundance Nitrogen-15 Spectra of Some 2-Amino-2-deoxy-D-hexose Derivatives

Abstract

The nitrogen-15 nuclear magnetic resonance spectra of some 2-amino-2-deoxj D-hexose drochlorides and 2-acetamido-2-deoxy-D-hexoses and N-benzoyl-D-glucosamine are reported. The differences in chemical shifts for the various hexopyranose structures are discussed in terms of steric, stereoelectronic, and hydrogen-bonding effects. These model compounds were used to study substituent effects related to amino sugar containing polysaccharides and antibiotics.

Additional Information

© 1977 American Chemical Society. Received September 28, 1976. Supported by the Public Health Service, Research Grant GM-11072, from the Division of General Medical Sciences, and by the National Science Foundation.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023