Published January 1980
| public
Journal Article
Proximity Effects on Nitrogen-15 Chemical Shifts of 8-Substituted 1-Nitronaphthalenes and 1-Naphthylamines
- Creators
- Schuster, Ingeborg I.
- Roberts, John D.
Chicago
An error occurred while generating the citation.
Abstract
^(15)N chemical shifts of several substituted 1-nitronaphthalenes and 8-substituted 1-naphthylamines have been determined and, in general, the substituent effects are unexpectedly small. The high-field shift of the amine nitrogen of 8-nitro-1-aminonaphthalene may indicate a degree of σ complexing between the amino group and the proximate substituents of the type suggested by Dunitz. The smallness of the other substituent effects may be the result of mutual cancellation of opposing larger effects.
Additional Information
© 1980 American Chemical Society. Received June 4, 1979. Supported by the National Science Foundation and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Sciences.Additional details
- Eprint ID
- 60835
- DOI
- 10.1021/jo01290a016
- Resolver ID
- CaltechAUTHORS:20151007-073141214
- NSF
- U.S. Public Health Service (USPHS)
- GM-11072
- Created
-
2015-10-07Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 6041