Published October 1, 1981
| public
Journal Article
Isotope Scrambling with ^(15)N-Labeled Azide Ion and p-Toluenesulfonyl Azide
- Creators
- Casewit, Carla
- Wenninger, J.
- Roberts, John D.
Chicago
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Abstract
p-Toluenesulfonyl azide (1) reacts with azide ion in dimethyl sulfoxide solution to form p-toluenesulfinate anion and dinitrogen (eq 1, Ts = 4-CH_3C_6H_4SO_2).^2 For a determination of whether TsN_3+N_3 → Ts + 3N_2 (1) or not there are solvent effects on this reaction, it has been studied in other solvents by ^(15)N NMR spectroscopy using potassium azide-1,3-^(15)N_1 (99%) as a tracer.
Additional Information
© 1981 American Chemical Society. Received April 2, 1981. Supported by the National Science Foundation. IBM Graduate Fellow 1979-1980. DAAD Postdoctoral Fellow, 1980-1981.Additional details
- Alternative title
- Isotope scrambling with nitrogen-15-labeled azide ion and p-toluenesulfonyl azide
- Eprint ID
- 60794
- DOI
- 10.1021/ja00410a058
- Resolver ID
- CaltechAUTHORS:20151006-073240179
- NSF
- IBM Graduate Fellow
- Deutscher Akademischer Austauschdienst (DAAD)
- Created
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2015-10-06Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field