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Published August 1950 | public
Journal Article

Solvolytic Reactivities of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides. Possible Steric Requirements for Hyperconjugative Resonance

Abstract

The present investigation is concerned with the determination and interpretation of the solvolytic reactivities of nortricyclyl (I), endo-dehydronorbornyl (II), exo-dehydronorbornyl (III), endonorbornyl (IV) and exo-norbornyl (V) halides. This series of structurally similar compounds provides an almost unique opportunity to observe the relationship between stereochemistry and solvolytic reactivities in alicyclic halides.

Additional Information

© 1950 American Chemical Society. Received June 1, 1950. Supported in part by the joint program of the Office of Naval Research and the Atomic Energy Commission.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023