Published September 28, 2015
| Supplemental Material
Journal Article
Open
Heterometallic Effects in Trinuclear Complexes Supported by p-Terphenyl Diphosphine Ligands
Abstract
A series of isostructural trinuclear complexes of metal composition Pd_2Fe, Pd_2Co, and Ni_2Fe was synthesized in a stepwise fashion. Using dinuclear precursors (Pd^I_2 and Ni_^I_2) supported by p-terphenyl diphosphine ligands allowed for the selective incorporation of a single additional metal center. The effects of both metal composition and ligand electronics on cluster properties were studied. These results highlight the importance of metal–metal interactions in mixed-metal sites of structurally analogous clusters.
Additional Information
© 2015 American Chemical Society. Received: July 6, 2015. Publication Date (Web): September 8, 2015. We thank Lawrence M. Henling, Mike Takase, and Michael W. Day for crystallographic assistance. We are grateful to Caltech and NSF (CHE-1151918) for funding. T.A. is grateful for Sloan, Cottrell, and Dreyfus fellowships. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to Caltech, CHE0639094. The authors declare no competing financial interest.Attached Files
Supplemental Material - om5b00579_si_001.pdf
Supplemental Material - om5b00579_si_002.cif
Files
om5b00579_si_001.pdf
Files
(19.6 MB)
| Name | Size | Download all |
|---|---|---|
|
md5:9acf95ea7189401795eca55a4939b495
|
1.1 MB | Preview Download |
|
md5:e257a326bc14aa347ac4b17ac63db4e3
|
18.5 MB | Download |
Additional details
- Eprint ID
- 60228
- DOI
- 10.1021/acs.organomet.5b00579
- Resolver ID
- CaltechAUTHORS:20150914-124302805
- CHE-1151918
- NSF
- Alfred P. Sloan Foundation
- Cottrell Scholar of Research Corporation
- Camille and Henry Dreyfus Foundation
- CHE-0639094
- NSF
- Created
-
2015-09-14Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field