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Published December 17, 1969 | public
Journal Article

Unusual slopes of free energy plots in kinetics

Abstract

Theoretical equations are used to comment on the relation between the slope of activation free energy-standard free energy of reaction plots and the concept of the position of the transition state along the reaction coordinate. The equations are then used to consider some recent experimental findings of unusual Brønsted coefficients.

Additional Information

© 1969 American Chemical Society. Received April 1, 1969. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, and to the National Science Foundation for their support of this research.

Additional details

Created:
August 19, 2023
Modified:
October 23, 2023