Inhomogeneous screening near a dielectric interface

Abstract

Screening is one of the most important concepts in the study of charged systems. Near a dielectricinterface, the ion distribution in a salt solution can be highly nonuniform. Here, we develop a theory that self-consistently treats the inhomogeneous screening effects. At higher concentrations when the bulk Debye screening length is comparable to the Bjerrum length, the double layerstructure and interfacial properties are significantly affected by the inhomogeneous screening. In particular, the depletion zone is considerably wider than that predicted by the bulk screening approximation or the WKB approximation. The characteristic length of the depletion layer in this regime scales with the Bjerrum length, resulting in a linear increase of the negative adsorption of ions with concentration, in agreement with experiments. For asymmetric salts, inhomogeneous screening leads to enhanced charge separation and surface potential.

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