Published September 24, 1971
| public
Journal Article
Xenon as a Nucleophile in Gas-Phase Displacement Reactions: Formation of the Methyl Xenonium Ion
- Creators
- Holtz, David
-
Beauchamp, J. L.
Chicago
An error occurred while generating the citation.
Abstract
Xenon undergoes reaction with protonated methyl fluoride in the gas phase to form abundant quantities of the stable methyl xenonium ion, CH_3Xe^+. Estimated values for the xenon-carbon and krypton-carbon bond strengths in the rare gas-methyl molecular ions are 43 ± 8 and 21 ± 15 kilocalories per mole, respectively.
Additional Information
© 1971 American Association for the Advancement of Science. Received 7 June 1971. Work supported in part by the U.S. Atomic Energy Commission under grant AT(04-3)67-8. Contribution No. 4328 from the California Institute of Technology.Additional details
- Eprint ID
- 59047
- DOI
- 10.1126/science.173.4003.1237
- Resolver ID
- CaltechAUTHORS:20150729-081841016
- Atomic Energy Commission
- AT(04-3)67-8
- Created
-
2015-07-29Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 4328