Published September 27, 1982
| public
Book Section - Chapter
Further Developments in Electron Transfer
- Creators
-
Marcus, R. A.
- Siders, Paul
Chicago
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Abstract
The inverted region in electron transfer reactions is studied for the reaction of electronically-excited ruthenium(II) tris-bipyridyl ions with various metal(III) tris-bipyridyl complexes. Numerical calculations for the diffusion-reaction equation are summarized for the case where electron transfer occurs over a range of distances. Comparison is made with the experimental data and with a simple approximation. The analysis reveals some of the factors which can cause a flattening of the ln k_(obs) versus ΔG^O curve in the inverted region. Ways of improving the chance of observing the effect are discussed.
Additional Information
© 1982 American Chemical Society. Received April 21, 1982. Publication Date (Print): July 23, 2009. It is a pleasure to acknowledge support of this research by a grant from the National Science Foundation. Contribution No. 6494 from the California Institute of Technology.Additional details
- Eprint ID
- 58738
- Resolver ID
- CaltechAUTHORS:20150701-132931351
- NSF
- Created
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2015-07-01Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Series Name
- ACS Symposium Series
- Series Volume or Issue Number
- 198
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 6494