Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published 1985 | public
Book Section - Chapter

Aspects of Intramolecular Dynamics in Chemistry

Abstract

The role of chaotic and quasiperiodic behavior of isolated molecules is discussed. The quantum analog of classical quasi- periodic states appears to be relatively well understood. A possible quantum analog of classical chaotic behavior is described, using overlapping quantum mechanical Fermi resonances as a way of generating irregularities. The relation of these Fermi resonances to avoided crossings in eigenvalue plots and to various treatments of intramolecular dynamics in the chemical literature is outlined.

Additional Information

© 1985 Springer International Publishing. It is a pleasure to acknowledge the support of this research by a grant from the National Science Foundation. Contribution No. 6894 from the California Institute of Technology.

Additional details

Created:
August 19, 2023
Modified:
January 13, 2024