Published 1987
| public
Book Section - Chapter
Solvent Dynamical and Symmetrized Potential Aspects of Electron Transfer Rates
- Creators
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Marcus, R. A.
Chicago
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Abstract
Recent experiments on very fast electron transfers have provided evidence for slow solvent dynamics under such conditions. The role of the vibrational motion of the reactants is included in the present treatment. The overall decay can be single- or multi-exponential. A simple approximate expression is given for a characteristic reaction time. The "symmetrization" approximation in the cross-relation is also discussed.
Additional Information
© 1987 by D. Reidel Publishing Company. The support of this research by the National Science Foundation is gratefully acknowledged. Carl and Ingrid, we salute you, and extend our very best wishes for the future.Additional details
- Eprint ID
- 58696
- Resolver ID
- CaltechAUTHORS:20150630-094059392
- NSF
- Created
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2015-06-30Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7396