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Published 1988 | public
Book Section - Chapter

On the Statistical Theory of Unimolecular Processes

Abstract

In recent years there has been an increasing use of laser spectroscopic and other techniques to investigate unimolecular dissociations of molecules, both to initiate a dissociation and to measure the formation of the individual quantum states of the immediate reaction products. This chapter is concerned with a description of statistical theories used to calculate the rates of such dissociations, for example, of a molecule AB, AB → A + B, and to calculate the distribution of the quantum states of the fragments A and B.

Additional Information

© 1988 by John Wiley & Sons, Inc. Published Online: 14 Mar 2007. NSERC of Canada University Research Fellow. It is a pleasure to acknowledge the support of this research by the Natural Sciences and Engineering Research Council of Canada (D.M.W.) and by the National Science Foundation (R.A.M.).

Additional details

Created:
August 22, 2023
Modified:
January 13, 2024