Published June 10, 1986
| public
Journal Article
Solvent dynamics and vibrational effects in electron transfer reactions
- Creators
-
Marcus, R. A.
- Sumi, H.
Chicago
An error occurred while generating the citation.
Abstract
Intramolecular vibrational effects can modify considerably the effect of solvent dynamics on the rates of electron transfer reactions, even for a fixed free energy barrier. Results of a previous paper by the authors are applied in an approximate way to provide a simplified formula for the reaction rate. The formula includes these effects and reduces to a well-known one of Kramers under a appropriate conditions and when, in addition, vibrational effects are absent.
Additional Information
© 1986 Eisevier Sequoia S.A. Received 2nd January 1986. It is a pleasure to acknowledge the support of this research by the National Science Foundation.Additional details
- Eprint ID
- 58324
- Resolver ID
- CaltechAUTHORS:20150617-130217766
- NSF
- Created
-
2015-06-17Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7347